Surfactants in the sea-surface microlayer and their contribution to atmospheric aerosols around coastal areas of the Malaysian peninsula

Surfactants in the sea-surface microlayer and their contribution to atmospheric aerosols around coastal areas of the Malaysian peninsula. Marine Pollution Bulletin, 60. pp. 1584-1590. ISSN 0025-326X (2010)



Abstract

The solvent-extractable compounds of urban airborne particulate matter were analyzed to determine the distributions of homologous and biomarker tracers. Samples were collected by high-volume air filtration during the haze episode of 1997 around the University of Malaya campus near Petaling Jaya, a suburb of Kuala Lumpur, Malaysia. These results show that the samples contain n-alkanes, n-alkan-2-ones, n-alkanols, methyl n-alkanoates, n-alkyl nitriles, n-alkanals, n-alkanoic acids, levoglucosan, PAHs, and UCM as the dominant components, with minor amounts of terpenoids, glyceryl esters and sterols, all derived from natural biogenic sources (vascular plant wax), from burning of biomass, and from anthropogenic utilization of fossil fuel products (lubricating oil, vehicle emissions, etc.).
Some compositional differences are observed in the samples and greater atmospheric concentrations were found for almost all organic components in the samples collected near a roadway. The results interpreted in terms of major sources are due to local build-up of organic contaminants from vehicular emissions, smoke from biomass burning, and natural background as a result of the atmospheric stability during the haze episodes. The organic components transported in from areas outside the region, assuming all smoke components are external to the city, amount to about 30% of the total organic particle burden.

Item Type: Article
Keywords: Surface, Surfactants, Coastal area Sea-, Sea-Surface microlayer, Atmospheric Aerosol
Taxonomy: By Subject > Applied Sciences > Chemistry
By Subject > Applied Sciences > Environmental Technology
Local Content Hub: Subjects > Applied Sciences
Depositing User: Mohd Fadhli Samsudin
Date Deposited: 08 Apr 2021 06:42
Last Modified: 08 Apr 2021 06:42
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